Isobutyl Vinyl Ether Polymerization

Cationic polymerization of isobutyl vinyl ether ibve was examined using a variety of metal halides.

Isobutyl vinyl ether polymerization.

Living cationic polymerization of isobutyl vinyl ether by the cf3co2h sncl4 nbu4ncl system in situ direct analysis of the growing species by1h 13c and19f nmr spectroscopy. Living cationic polymerization of isobutyl vinyl ether by hydrogen chloride lewis acid initiating systems in the presence of salts. In this work we attempted to develop fast living cationic polymerization of isobutyl vinyl ether ibve tailored by reduced single nucleophile in microflow system. In order to elucidate the reason for the considerable difference in the activation energies for the propagation of styrene and isobutyl vinyl ether ibve radiation induced copolymerization of.

Judging from the precipitation temperature in the polymerization of vinyl isobutyl ether catalyzed by bf 3 oet 2 at 78 c the polyvinyl ethers obtained from a homogeneous polymerization system are of a more isotactic structure than those obtained from a related heterogeneous system at low monomer concentration. Journal of physical organic chemistry 1995 8 4 282 292. A variety of coinitiators were used in conjunction with the ibve hcl adduct acting as a cationogen. Cationic polymerization of isobutyl vinyl ether ibve in aqueous media suspension dispersion or emulsion using mainly bf 3 oet 2 as a co initiator is reported.

The application of living cationic polymerization suffers from complex and costly additives as well as low productivity. In the presence of 2 6 dimethylpyridine as an added base living cationic polymerization of isobutyl vinyl ether was achieved in n hexane at 0 to 40 c with the 1 isobutoxy ethyl acetate. Cationic polymerization of isobutyl vinyl ether ibve in an ionic liquid 1 octyl 3 methylimidazolium tetrafluoroborate omim bf 4 was thoroughly examined at 0 c.